2024
Reabsorption-Free Scintillating Hetero-Ligand MOF Crystals Activated by Ultrafast Energy Transfer
M. Orfano, J. Perego, C. X. Bezuidenhout, I. Villa, R. Lorenzi, B. Sabot, S. Pierre, S. Bracco, S. Piva, A. Comotti and A. Monguzzi
Adv. Funct. Mater. 2024, 2404480
Solid State Machinery of Multiple Dynamic Elements in a Metal–Organic Framework
J. Perego, A. Daolio, C. X. Bezuidenhout, S. Piva, G. Prando, B. Costarella, P. Carretta, L. Marchiò, D. Kubicki, P. Sozzani, S. Bracco and A. Comotti
Angew. Chem. Int. Ed. 2024, 63, e202317094
2023
Construction of Multi-Stimuli Responsive Highly Porous Switchable Frameworks by In-Situ Solid-State Generation of Spiropyran Switches
J. Sheng, J. Perego, S. Bracco, W. Czepa, W. Danowski, S. Krause, P. Sozzani, A. Ciesielski, A. Comotti and B. L. Feringa
Adv. Mater. 2024, 36, 2305783
Construction of a three-state responsive framework from a bistable photoswitch
J. Sheng, J. Perego, W. Danowski, S. Bracco, S. Chen, X. Zhu, C. X. Bezuidenhout, S. Krause, W. R. Browne, P. Sozzani, A. Comotti and B. L. Feringa
Chem 2023, 9, 2701-2716
Efficient radioactive gas detection by scintillating porous metal–organic frameworks
M. Orfano, J. Perego, F. Cova, C. X. Bezuidenhout, S. Piva, C. Dujardin, B. Sabot, S. Pierre, P. Mai, C. Daniel, S. Bracco, A. Vedda, A. Comotti and A. Monguzzi
Nature Photonics 2023, 17, 672-678
Benchmark Dynamics of Dipolar Molecular Rotors in Fluorinated Metal-Organic Frameworks
J. Perego, C. X. Bezuidenhout, S Bracco, S. Piva, G. Prando, C. Aloisi, P. Carretta, J. Kaleta, T. P. Le, P. Sozzani, A. Daolio, and A. Comotti
Angew. Chem. Int. Ed. 2023, 62, e202215893
2022
Phosphine Oxide Porous Organic Polymers Incorporating Cobalt(II) Ions: Synthesis, Characterization, and Investigation of H2 Production
G. Bonfant, D Balestri, J. Perego, A. Comotti, S. Bracco, M. Koepf, M. Gennari, L. Marchio
ACS Omega 2022, 7, 7, 6104–6112
Collective dynamics of molecular rotors in periodic mesoporous organosilica: a combined solid-state 2H-NMR and molecular dynamics simulation study
A. De Nicola, A. Correa, S. Bracco, J. Perego, P. Sozzani, A. Comotti, G. Milano
Phys. Chem. Chem. Phys. 2022, 24, 666-673
Highly luminescent scintillating hetero-ligand MOF nanocrystals with engineered Stokes shift for photonic applications
J. Perego, C. Bezuidenhout, I. Villa, F. Cova, R. Crapanzano, I. Frank, F. Pagano, N. Kratochwill, E. Auffray, S. Bracco, A. Vedda, C. Dujardin, P. Sozzani, F. Meinardi, A. Comotti, A. Monguzzi
Nature Communications 2022, 13, 3504
2021
Cascade Dynamics of Multiple Molecular Rotors in a MOF: Benchmark Mobility at a Few Kelvins and Dynamics Control by CO2
J. Perego, C. Bezuidenhout, S. Bracco, G. Prando, L. Marchio, M. Negroni, P. Carretta, P. Sozzani, A. Comotti
J. Am. Chem. Soc. 2021, 143, 33, 13082–13090
Composite fast scintillators based on high-Z fluorescent metal–organic framework nanocrystals
J. Perego, I. Villa, A. Pedrini, E. Padovani, R. Crapanzano, A. Vedda, C. Dujardin, C. Bezuidenhout, S. Bracco, P. Sozzani, A. Comotti, L. Gironi, M. Beretta, M. Salomoni, N. Kratochwil, S. Gundacker, E. Auffray, F. Meinardi, A. Monguzzi
Nature Photonics 2021, 15, 393–400
Calixarene-based porous 3D polymers and copolymers with high capacity and binding energy for CO2, CH4 and Xe capture
A. Pedrini, J. Perego, S. Bracco, C. Bezuidenhout, P. Sozzani, A. Comotti
J. Mater. Chem. A 2021, 9, 27353-27360
Anionic Polymerization in Porous Organic Frameworks: A Strategy to Fabricate Anchored Polymers and Copolymers
J. Perego, S. Bracco, A. Comotti, D. Piga, I. Bassanetti, P. Sozzani
Angew. Chem. Int. Ed. 2021, 60, 6117–6123
2020
Reorientable fluorinated aryl rings in triangular channel Fe-MOFs: an investigation on CO2–matrix interactions
J. Perego, C. Bezuidenhout, A. Pedrini, S. Bracco, M. Negroni, A. Comotti, P. Sozzani
J. Mater. Chem. A 2020, 8, 11406-11413
Modulation of porosity in a solid material enabled by bulk photoisomerization of an overcrowded alkene
F. Castiglioni, W. Danowski, J. Perego, F. Leung, P. Sozzani, S. Bracco, S. Wezenberg, A. Comotti, B. Feringa
Nature Chemistry 2020, 12, 595–602
Fast motion of molecular rotors in metal–organic framework struts at very low temperatures
J. Perego, S. Bracco, M. Negroni, C. Bezuidenhout, G. Prando, P. Carretta, A. Comotti, P. Sozzani
Nature Chemistry 2020, 12, 845–851
Carbonization of single polyacrylonitrile chains in coordination nanospaces
X. Zhang, T. Kitao, D. Piga, R. Hongu, S. Bracco, A. Comotti, P. Sozzani, T. Uemura
Chem. Sci. 2020, 11, 10844-10849
Molecular Rotors in a Metal-Organic Framework: Muons on a Hyper-Fast Carousel
G. Prando, J. Perego, M. Negroni, M. Riccò, S. Bracco, A. Comotti, P. Sozzani, P. Carretta
Nano Lett. 2020, 20, 10, 7613–7618
Synthesis, crystal structure, and optical properties of fluorinated poly(pyrazole) ligands and in silico assessment of their affinity for volatile organic compounds
A. Pedrini, A. Maspero, S. Bracco, A. Comotti, S. Galli, L. Marchio, L. Nardo, A. Penoni, L. Scapinello, P. Sozzani, G. Vesco, M. Mella
New J. Chem. 2020, 44, 6443-6455
Visible-light-driven rotation of molecular motors in a dual-function metal-organic framework enabled by energy transfer
W. Danowski, F. Castiglioni, A. Sardjan, S. Krause, L. Pfeifer, D. Roke, A. Comotti, W. Browne, B. Feringa
J. Am. Chem. Soc. 2020, 142, 19, 9048–9056
2019
A double helix of opposite charges to form channels with unique CO2 selectivity and dynamics
G. Xing, I. Bassanetti, S. Bracco, M. Negroni, C. Bezuidenhout, T. Ben, P. Sozzani, A. Comotti
Chem. Sci. 2019, 10, 730
Fluorinated porous organic frameworks for improved CO2 and CH4 capture
A. Comotti, F. Castiglioni, S. Bracco, J. Perego, A. Pedrini, M. Negroni, P. Sozzani
Chem. Commun. 2019, 55, 8999-9002
Tight Xenon Confinement in a Crystalline Sandwich-like Hydrogen-Bonded Dimeric Capsule of a Cyclic Peptide
A. Pizzi, H. Ozores, M. Calvelo, R. Garcia-Fandino, M. Amorin, N. Demitri, G. Terraneo, S. Bracco, A. Comotti, P. Sozzani, C. Bezuidenhout, P. Metrangolo, J. Granja
Angew. Chem. Int. Ed. 2019, 58, 14472-14476
Engineering Porous Emitting Framework Nanoparticles with Integrated Sensitizers for Low-Power Photon Upconversion by Triplet Fusion
J. Perego, J. Pedrini, C. Bezuidenhout, P. Sozzani, F. Meinardi, S. Bracco, A. Comotti, A. Monguzzi
Adv. Mater. 2019, 31, 1903309
2018
Atomistic Model of Realistic Crystalline Mesoporous Organosilica Materials Including Nanochannels
A. De Nicola, A. Correa, A. Comotti, P. Sozzani, G. Milano
J. Phys. Chem. C 2018, 122, 31, 17825–17835
Multifunctional Organosulfonate Anions Self-Assembled with Organic Cations by Charge-Assisted Hydrogen Bonds and the Cooperation of Water
G. Xing, I. Bassanetti, T. Ben, S. Bracco, P. Sozzani, L. Marchiò, A. Comotti
Cryst. Growth Des. 2018, 18, 4, 2082–2092
Expandable porous organic frameworks with built-in amino and hydroxyl functions for CO2 and CH4 capture
J. Perego, D. Piga, S. Bracco, P. Sozzani, A. Comotti
Chem. Commun. 2018, 54, 9321-9324
Flexible porous molecular materials responsive to CO2, CH4 and Xe stimuli
I. Bassanetti, S. Bracco, A. Comotti, M. Negroni, C. Bezuidenhout, S. Canossa, P. Mazzeo, L. Marchió, P. Sozzani
J. Mater. Chem. A 2018, 6, 14231-14239
Changing the Dress to a MOF through Fluorination and Transmetalation. Structural and Gas-Sorption Effects
D. Balestri, I. Bassanetti, S. Canossa, C. Gazzurelli, A. Bacchi, S. Bracco, A. Comotti, P. Pelagatti
Cryst. Growth Des. 2018, 18, 11, 6824–6832
2017
Solid-State NMR of Supramolecular Materials
A. Comotti, S. Bracco, P. Sozzani
in: Comprehensive Supramolecular Chemistry II, (pp. 75-99). Elsevier.
Porous dipeptide crystals as volatile-drug vessels
S. Bracco, D. Asnaghi, M. Negroni, P. Sozzani, A. Comotti
Chem. Commun., 2018, 54, 148-151
CO2 regulates molecular rotor dynamics in porous materials
S. Bracco, T. Miyano, M. Negroni, I. Bassanetti, L. Marchio, P. Sozzani, N. Tohnai, A. Comotti
Chem. Commun., 2017, 53, 7776-7779
Molecular tectonics: Gas adsorption and chiral uptake of (L)- and (D)-tryptophan by homochiral porous coordination polymers
D. Asnaghi, R. Corso, P. Larpent, I. Bassanetti, A. Jouaiti, N. Kyritsakas, A. Comotti, P. Sozzani, M. Hosseini
Chem. Commun., 2017, 53, 5740-5743
Porous 3D polymers for high pressure methane storage and carbon dioxide capture
S. Bracco, D. Piga, I Bassanetti, J. Perego, A. Comotti, P Sozzani
J. Mater. Chem. A 2017, 5, 10328-10337
Ultrafast Molecular Rotors and Their CO2 Tuning in MOFs with Rod-Like Ligands
S. Bracco, F. Castiglioni, A. Comotti, S. Galli, M. Negroni, A. Maspero, P. Sozzani
Chem. Eur. J. 2017, 23, 11210-11215
2016
Recognition of 1,3-Butadiene by a Porous Coordination Polymer
K. Kishida, Y. Okumura, Y. Watanabe, M. Mukoyoshi, S. Bracco, A. Comotti, P. Sozzani, S. Horike, S. Kitagawa
Angew. Chem. Int. Ed. 2016, 55, 13784-13788
Molecular Rotors Built in Porous Materials
A. Comotti, S. Bracco, P. Sozzani
Acc. Chem. Res. 2016, 49, 9, 1701–1710
2015
Polimerizzazioni allo stato solido in materiali nanoporosi
S. Bracco, D. Asnaghi, P. Sozzani, A. Comotti
La Chimica e L’Industria 2015, 3, 42-47
Confined Polymerization in Highly Ordered Mesoporous Organosilicas
A. Comotti, S. Bracco, M. Beretta, J. Perego, M. Gemmi, P. Sozzani
Chem. Eur. J. 2015, 21, 18209-18217
Photoinduced reversible switching of porosity in molecular crystals based on star-shaped azobenzene tetramers
M. Baroncini, S. D’Agostino, C. Bergamini, P. Ceroni, A. Comotti, P. Sozzani, I Bassanetti, F. Grepioni, T. Hernandez, S. Silvi, M. Venturi, A. Credi
Nature Chemistry 2015, 7, 634–640
Confinement of single polysilane chains in coordination nanospaces
T. Kitao, S. Bracco, A. Comotti, P. Sozzani, M. Naito, S. Seki, T. Uemura, S. Kitagawa
J. Am. Chem. Soc. 2015, 137, 15, 5231–5238
Porous materials explored by hyperpolarized xenon NMR
P. Sozzani, S. Bracco, A. Comotti
Hyperpolarized Xenon-129 Magnetic Resonance: Concepts, Production, Techniques and Applications. Royal Society of Chemistry
Microporous Molecular Materials from Dipeptides Containing Non-proteinogenic Residues
V. Yadav, A. Comotti, P. Sozzani, S. Bracco, T. Bonge Hansen, M. Hennum, C. Görbitz
Angew. Chem. Int. Ed. 2015, 54, 15684-15688
Dipolar rotors orderly aligned in mesoporous fluorinated organosilica architectures
S. Bracco, M. Beretta, A. Cattaneo, A. Comotti, A. Falqui, K. Zhao, C. Rogers, P. Sozzani
Angew. Chem. Int. Ed. 2015, 54, 4773-4777
2014
Molecular Rotors in Porous Organic Frameworks
A. Comotti, S. Bracco, T. Ben, S. Qiu, P. Sozzani
Angew. Chem. Int. Ed. 2014, 53, 1043-1047
Porous molecular crystals by macrocyclic coordination supramolecules
I. Bassanetti, A. Comotti, P. Sozzani, S. Bracco, G. Calestani, F. Mezzadri, L. Marchiò
J. Am. Chem. Soc. 2014, 136, 42, 14883–14895
Microporous hyper-cross-linked aromatic polymers designed for methane and carbon dioxide adsorption
M. Errahali, G. Gatti, L. Tei, G. Paul, G. Rolla, L. Canti, A. Fraccarollo, M. Cossi, A. Comotti, P. Sozzani, L. Marchese
J. Phys. Chem. C 2014, 118, 49, 28699–28710
When Long Bis (pyrazolates) Meet Late Transition Metals: Structure, Stability and Adsorption of MOFs Featuring Large Parallel Channels
S. Galli, A. Maspero, C. Giacobbe, G. Palmisano, L. Nardo, A. Comotti, I. Bassanetti, P. Sozzani, M. Masciocchi
J. Mater. Chem. A 2014, 2, 12208-12221
The first route to highly stable crystalline microporous zirconium phosphonate metal–organic frameworks
M. Taddei, F. Costantino, F. Marmottini, A. Comotti, P. Sozzani, R. Vivani
Chem. Commun. 2014, 50, 14831-14834
Crystallization of nanoheterogeneities in Ga-containing germanosilicate glass: Dielectric and refractive response changes
A. Paleari, V. Sigaev, N. Golubev, E. Ignat’Eva, S. Bracco, A. Comotti, A. Azarbod, R. Lorenzi
Acta Materialia 2014, 70, 19-29
Oltre le molecole: un viaggio dalla chimica supramolecolare alla nanomedicina
D. Asnaghi, A. Comotti, P. Sozzani
La Chimica e L’Industria 2014, 7
2013
Highly ordered alignment of a vinyl polymer by host-guest cross-polymerization
G.Distefano, H. Suzuki, M. Tsujimoto, S. Isoda, S. Bracco, A. Comotti, P. Sozzani, T. Uemura, S. Kitagawa
Nature Chemistry 2013, 5, 335–341
Mohlau’s Anthradipyrazole Revisited: A New Look at an Old Molecular System
A. Maspero, G. Giovenzana, N. Masciocchi, G. Palmisano, A. Comotti, P. Sozzani, I. Bassanetti, L. Nardo
Cryst. Growth Des. 2013, 13, 11, 4948–4956
Synthesis, breathing, and gas sorption study of the first isoreticular mixed-linker phosphonate based metal-organic frameworks
M. Taddei, F. Costantino, A. Ienco, A. Comotti, P. Dau, S. Cohen
Chem. Commun. 2013, 49, 1315-1317
Engineering Switchable Rotors in Molecular Crystals with Open Porosity
